The CO2 that nature emits (from the ocean and vegetation) is balanced by natural absorptions (again by the ocean and vegetation). Therefore human emissions upset the natural balance, rising CO2 to levels not seen in at least 800,000 years. In fact, human emit 26 gigatonnes of CO2 per year while CO2 in the atmosphere is rising by only 15 gigatonnes per year - much of human CO2 emissions is being absorbed by natural sinks.
About 40% of human CO2 emissions are being absorbed, mostly by vegetation and the oceans. The rest remains in the atmosphere. As a consequence, atmospheric CO2 is at its highest level in 15 to 20 million years (Tripati 2009). A natural change of 100ppm normally takes 5,000 to 20.000 years. The recent increase of 100ppm has taken just 120 years.
Additional confirmation that rising CO2 levels are due to human activity comes from examining the ratio of carbon isotopes (eg ? carbon atoms with differing numbers of neutrons) found in the atmosphere. Carbon 12 has 6 neutrons, carbon 13 has 7 neutrons. Plants have a lower C13/C12 ratio than in the atmosphere. If rising atmospheric CO2 comes from fossil fuels, the C13/C12 should be falling. Indeed this is what is occurring (Ghosh 2003). The C13/C12 ratio correlates with the trend in global emissions.