Mill's surely isn't going to average the 18.4 MPG he is currently seeing, but even those numbers are inflated by him filling in for Tony for stretches and the Spurs general injuries woes.
Pop will surely shorten the rotation in the playoffs, but I don't see the wing players losing a lot of minutes. If anything, they will just be re-allocated as Pop goes into his small-ball rotations, especially if the Spurs go up against HOU, GSW, OKC, or MIA.
Pop will probably squeeze a big man out of the rotation, so goodbye Ayers, Baynes, and Bonner for the most part. With their vastly different but limited skill-sets, Pop will inject them as needed.
The starters are probably locked at Duncan, Splitter, Leonard, Green, Parker, unless Pop decides to go for his Splitter-Diaw swap against smaller teams. Their minutes will surely increase, along with Manu's, so that naturally will pull minutes from Mills, Marco, and Diaw. Even if the starters + Manu all get 34 MPG in the playoffs, that leaves 12 MPG for those three. Mills and Marco will see increased roles at the 2 and 3 spot, as will Diaw at the 3 and 4. Duncan and Splitter's increased minutes will take the place of the missing big.
That being said, I think Mills sees about 13 MPG in the playoffs.

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